It sounds like you might want a table:
If you explained what you are actually trying to achieve, then someone can probably help you.
"I would like to create a struct that looks like the attached example"
It has no meaning to request "a struct that looks like the attached example" because the visual representation of that structure depends entirely on the variable viewer, and not on the structure. How my MATLAB version might display that structure is not necessarily the same as how your MATLAB version displays it, the structure itself stores no formatting information at all, and it certainly does not store "row numbers" nor "column labels".
You seem to be confusing the visual representation of a structure with how it is stored.
