You have an extra comma, and one set of brackets of the wrong type, and wrong notation for column 5.
size(mydata{7,1},1)) - nnz(mydata{7,1}(:,5))
size(Array,1) asks for the number of rows in the array, and number of rows is going to be the same as the number of items that are in column 5.
But I would suggest
T = mydata{7,1)(:,5);
numberOfZeros = length(T) - nnz(T);