First you should extract the eigenvalues from the diagonal matrix (mainly for convenience):
vLambda = diag(Vect);
Then you want the sum of the "first two" for your P_i. Presumably "first two" means the two largest, though that's not made explicitly clear. Let's check where those are:
plot(vLambda,'.-')
So the last eigenvalues are the biggest. This gives us for P:
P = vLambda(end-1:end)/vLambda(end) + vLambda(end-1)
Then you're asked for the sum of P multiplied with acos(|u_i|). You should be able to figure that one out. Read the help and documentation of eig and think about what more you know about the eigenvectors (write these facts down in a list) and one fact of those can be used to some insight about acos.
Also since these questions make it seem as you are very new to matlab, I recommend you browse through the on-ramp material. It is designed to get you up and running as fast as possible.
HTH
