Based on my understanding of what you want to do, I think that the Simulation Data Inspector programmatic interface should help. Have you looked into using Simulink.sdi.compareRuns?
You can use the RelTol parameter of the Simulink.sdi.Signal objects for the relevant signals to set your 10% (0.1) tolerance.
Use the Simulink.sdi.DiffRunResult object returned by Simulink.sdi.compareRuns to access the relevant Simulink.sdi.DiffSignalResult objects. The Match parameter of the Simulink.sdi.DiffSignalResult object indicates whether the difference resulting from the comparison fell within the specified tolerance.
The example Analyze Simulation Data with Signal Tolerances on the Simulink.sdi.compareRuns page should help fill in the details.