for exp(-a*s)F(s) the Laplace inverse will be f(t-a)U(t-a). Then find inverse laplace of first 5/(s(s+a)) and then put (t-a) instead of t.
In Programming, Run a loop for no. of times you want to get samples. Say, I want to get 10 samples:
S12=[]; % It is am empty matrix in which I want to store my elements of all step response
for i=1:10
S12=[S12;5-5*exp(-0.2*(i-1.4))];
end