Try this:
X1 = [
1.994711e-02 5.978008e-02 9.961305e-02 1.394460e-01 1.792790e-01 2.191120e-01 2.589449e-01 2.987779e-01 3.386109e-01 3.784439e-01 4.182768e-01 4.581098e-01 4.979428e-01 5.377757e-01 5.776087e-01 6.174417e-01 6.572747e-01 6.971076e-01 7.369406e-01 7.767736e-01 8.166066e-01 8.564395e-01 8.962725e-01 9.361055e-01 9.759384e-01 ];
N1 = [
6.910998e-02 6.358135e-02 5.939631e-02 5.477412e-02 5.035550e-02 4.661832e-02 4.306543e-02 3.973325e-02 3.640108e-02 3.456677e-02 3.427749e-02 3.374177e-02 3.321890e-02 3.323176e-02 3.361105e-02 3.347819e-02 3.356605e-02 3.354248e-02 3.344391e-02 3.361105e-02 3.341176e-02 3.348248e-02 3.306890e-02 3.352534e-02 3.318676e-02 ];
% Plot N1
subplot(3,1,1);
y=bar(X1,N1,1.0);
xmin = min(X1);
xmax = max(X1);
xwid = xmax - xmin;
xmin = xmin - 0.5 * xwid / 25;
xmax = xmax + 0.5 * xwid / 25;
ymax = max(N1);
axis([xmin xmax 0 ymax])
xlabel('X1','FontWeight','bold','FontSize',12)
ylabel('Probabilities','FontWeight','bold','FontSize',12)
set(gca,'linewidth',2)
set(gca,'fontweight','bold')
set(gca,'fontsize',12)
% Plot Gaussian
subplot(3,1,2);
x = X1; %linspace(0, 1, length(X1));
g = exp(-(x-0.5).^2/(2*0.167^2))
% Make g the same height at the tallest N1
plot(x, g, 'r-', 'LineWidth', 3);
grid on;
% Plot both
subplot(3,1,3);
bar(X1,N1,1.0);
hold on;
% Make g the same height at the tallest N1
g = g * max(N1);
plot(x, g, 'r-', 'LineWidth', 3);
grid on;
![](https://www.mathworks.com/matlabcentral/images/broken_image.png)