Don't use the built-in min function. It's second return argument will only return the location of the first occurrence of the min value. A more robust and general solution is to use min() in combination with find():
vect =[ 2.6660 2.2852 10.0000 2.2852 3.2617 10.0000 10.0000 9.8532];
minValue = min(vect(:))
% Find all the rows and columns where that value occurs:
indexes = find(vect == minValue)
See how in this case, where the min occurred in two locations, it found both of them: one at vect(2) and another one at vect(4).
