I found out the answer
clear all; close all;
p = linspace(-1/2,1/2,100);
[X,Y,Z] = meshgrid(p,p,p); % box mesh
R = p(size(p,2))/2;
r = R/1.5;
alpha = deg2rad(45);
f = figure('visible','on');
theta = atan2(sqrt(X.^2+Y.^2),Z);
active = (X.^2 + Y.^2 + Z.^2 <= R^2) & (X.^2 + Y.^2 +Z.^2 >= r^2);
plot3(X(active),Y(active),Z(active),'o','MarkerFaceColor','blue');
active = (X.^2 + Y.^2 + Z.^2 <= R^2) & (X.^2 + Y.^2 +Z.^2 >= r^2) & (abs(theta) <= alpha);
hold on
plot3(X(active),Y(active),Z(active),'o','MarkerFaceColor','red');
saveas(f,'3d_patch','fig')