Hi there,
you can get a list of jar-files known to Matlab by executing: Return Java class path or specify dynamic path - MATLAB javaclasspath - MathWorks Deutschland. I am not aware that anything that shows classes.
However, you should consider that javaaddpath only adds libraries to the dynamic Java path (Add entries to dynamic Java class path - MATLAB javaaddpath - MathWorks Deutschland). For some Java features like events or for instance also database connections, the static path must be used (which is less convenient): Static Path of Java Class Path - MATLAB & Simulink - MathWorks Deutschland and Static Java classpath hacks - Undocumented Matlab
Thus. it may actually be that Matlab has the jar in the path but cannot execute anything with it, because it requires some callback features that are only available if everything was set up statically.