In the freqs call, the phase is wrapped. Unwrap it and freqs matches bode —
wp = 1;
ws = 1.2;
Rp = 0.2;
Rs = 25;
[n, Wn] = buttord(wp,ws,Rp,Rs,'s');
[num, den] = butter(n, Wn, 's');
sys = tf(num, den);
sys
figure
bode(sys)
figure
freqs(num,den, 1E+2)
Ax2 = get(subplot(2,1,2));
Line = Ax2.Children;
Ax2.Children.YData = rad2deg(unwrap(deg2rad(Line.YData)));
.