You can concatenate each element of your cell array using cat or convert the cell array to a regular array using cell2mat. Then save as a spreadsheet.
x = {[1;2;3], [10;11;12]} % sample data (cell size 1x2, each cell contains data 3x1)
y = cat(2, x{:})
y = cell2mat(x)
writematrix(y, 'table.xlsx');