numerical fft requires a shift if we want to visualize the spectrum with both negative and positive frequencies, scaling problem is not yet solved, however try the following version, the theoretical transformation is calculated using 2*pi*f instead of f :
close all;
clear all;
clc;
N = 100;
dt = 0.01;
Fs = 1/dt;
F = zeros(N,1);
n0 = 50;
for n = 1:N
F(n) = exp(-((n-n0)*dt)^2*(pi^2));
end
G_cmp = fft(F)/((N));
f_arr = Fs/2*linspace(-1,1,N);
syms t f
F_an = exp(-(t-n0*dt)^2*(pi^2));
G_an = fourier(F_an, t, 2*pi*f);
f1 = figure;
subplot(1,2,1)
p1 = plot(dt*(1:N), F);
%saveas(f1, 'pulse_time.png');
%f2 = figure;
subplot(1,2,2)
p2 = plot(f_arr, fftshift(2*abs(G_cmp)),'-+', f_arr, 2*abs(subs(G_an, 'f', f_arr)),'r--');
%saveas(f2, 'pulse_freq.png');
