The first error is matlab not being able to load the file for some reason. Maybe it is corrupted, maybe you're using an old version of matlab and it's saved in a newer format, maybe you don't have read permission. It's impossible for us to tell. Or maybe it's in a text format. Have you tried to do what matlab is suggesting?
The second error is because a variable in the mat file is an object of class SVMLightingClassifier. For matlab to load that correctly, it needs to see the code of SVMLightingClassifier (as it was when the mat file was saved). In the absence of such code matlab can't reconstruct the object and therefore just give you a number instead (which is completely useless). Unfortunately, only you can tell where to find that code. As far as I know it's not part of toolbox.