While you could indeed edit the code yourself so it does whatever you want, this whole thing is a very bad idea.
What if the xml is instead:
<XMLname attrib1="Some value">
<Element attrib2="Some other value">Some text</Element>
</XMLname>
Where does attrib2 go in the structure? You do need
s.XMLName.Element.Text = 'Some text';
s.XMLName.Element.Attributes.attrib2 = 'Some other value';
xml2struct exactly reflects the XML DOM. What you're asking breaks from it. It is correct that the text portion of an element should be identified by its own field.
Also, I don't understand why it would be causing problem for you. Why can't you adjust your code so it conform to the xml DOM?
