I don't have the toolbox needed for hextobinaryvector(), but I assume the binary vector is just that. Given this solution:
One can extend it to accept binary values expressed as logical vectors instead of character vectors simply:
d = logical([1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0]);
typecast(uint16(bin2dec(sprintf('%d',d))),'int16')