After line() call hold on and then plot
line(..................);
hold on;
% Plot triangle at (x_marker1, y_marker1).
plot(x_marker1, y_marker1, ...
'r^', 'MarkerSize', 20, 'LineWidth', 2);
% Plot + sign at at (x_marker2, y_marker2).
plot(x_marker2, y_marker2, ...
'r+', 'MarkerSize', 20, 'LineWidth', 2);
You can change the 'r*' to get different colors and markers, for example o=circle, d=diamond, .=dot, +=plus sign, s=square, etc..