The names of your variables are a little confusing ... You are starting with values being a double array and then wanting values to be a structure ...
To answer your question you can create a cell array with the same string n-times with deal.
doc deal
Specifically you can make a 1x5 cell array filename have the value saved in name with:
[filename{1:5}] = deal(name);
you may want to consider a structure array ...
values = struct('value', mat2cell(values, 1, ones(5, 1)), 'filename', name)
