subs(dsScap) is not a command. subs() tells MATLAB to process the input expression and return the expression with substitutions. The input variable is not changed. You can assign the result of subs() to a variable.
Because the input variable is not changed, if you have used the input variable elsewhere (such as taking its derivative) then those other locations are not changed.
If you were to assign the result of the subs() on top of the original variable, then other places that used the variable before would also not be changed -- not until you used subs() on them. When you use a symbolic variable in an expression, the symbolic variable is "captured" in the state it was at the time it was used. For example if you have
syms x y z
z = x + y
y = 2 * x
then z will still be x + y, and would not become 3 * x until you did a subs(z)
